It’s all up to you.....but personally, if you’ve owned the car since new, and have kept up on the maintenance, you probably “really” don’t need to use it in the engine oil.......as mentioned, MMO is compatible with synthetics, but MMO themselves don’t recommend keeping MMO in the crankcase for more than 3000 miles....so if you want to add the MMO to the “last 3000” of your intended OCI, I don’t see a problem with that.....
And this will be the first time I’ve ever recommended this LOL....simply because yes, under “most” circumstances it’s best to use MMO in freshly changed oil....but in the case of a synthetic, surely you want to take the OCI out to 5000+ miles.....and adding at the start, would have you changing it at 3k (if you followed MMO’s guidelines anyways).
Also note, keep an eye on the oil level after adding the oil, there’s been some who have experienced “oil burn off” when using MMO....myself included. So even if you add it at the last 3k of your OCI, keep an eye on your oil level, say every other fuel up - I always keep the pump attended, and will pop the hood before gassing up, and check the oil level AFTER fueling up, giving the oil plenty of time to drain down to the pan while I’m pumping